revision date 25/03/2011 safety data sheet TT-P-1757B type i class c yellow according to regulation (ec) no 1907/2006 1 identification of the substance/preparation and of the company/undertaking product name TT-P-1757B type i class c yellow application paint randolph products inc manufacturer 33 haynes circle chicopee ma 01020 usa 001 413 592 4191 001 413 594 7321 haas group international scm ltd supplier newton road, crawley, west sussex, rh10 9ty united kingdom 44 (0) 1293 459500 +1 703 527 3887 chemtrec emergency 24hrs 44 (0) 1293 459600 datasheet@haasgroupintl.com contact person talisha james 2 hazards identification harmful if swallowed. vapours may cause drowsiness and dizziness. harmful: may cause lung damage if swallowed. irritating to eyes. may cause sensitisation by skin contact. may cause cancer. very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. classification (1999/45) carc. cat. 2;r45. xn;r22, r65. xi;r36. r43. n;r50/53. r67. 3 composition/information on ingredients ec no. name classification (67/548/eec) cas-no. content % 201-159-0 butanone f;r11 xi;r36 r66 r67 78-93-3 10-30% 200-578-6 ethanol f;r11 64-17-5 10-30% 201-148-0 iso-butanol r10 xi;r37/38,r41 r67 78-83-1 5-10% mineral spirits xn;r65. 8032-32-4 5-10% 232-489-3 stoddard solvent; low boiling point naphtha - unspecified carc. cat. 2;r45 xn;r65 8052-41-3 1-5% talc xn;r20. 14807-96-6 5-10% 203-625-9 toluene f;r11 repr. cat. 3;r63 xn;r48/20,r65 xi;r38 r67 108-88-3 1-5% zinc potassium chromate carc. cat. 1;r45. xn;r22. n;r50/53. r43. 11103-86-9 30-60% the full text for all r-phrases is displayed in section 16 4 first-aid measures inhalation move the exposed person to fresh air at once. rinse nose and mouth with water. get medical attention if any discomfort continues. ingestion never make an unconscious person vomit or drink fluids! rinse mouth thoroughly. get medical attention if any discomfort continues. skin contact remove affected person from source of contamination. remove contaminated clothing. wash the skin immediately with soap and water. get medical attention if any discomfort continues. 6 1 / free datasheet http://
revision date 25/03/2011 TT-P-1757B type i class c yellow eye contact remove victim immediately from source of exposure. make sure to remove any contact lenses from the eyes before rinsing. promptly wash eyes with plenty of water while lifting the eye lids. continue to rinse for at least 15 minutes and get medical attention. 5 fire-fighting measures extinguishing media this product is not flammable. fire can be extinguished using: carbon dioxide (co2). foam. halon. dry chemicals. special fire fighting procedures avoid breathing fire vapours. unusual fire & explosion hazards no unusual fire or explosion hazards noted. protective measures in fire self contained breathing apparatus and full protective clothing must be worn in case of fire. 6 accidental release measures personal precautions wear protective clothing as described in section 8 of this safety data sheet. environmental precautions spillages or uncontrolled discharges into watercourses must be immediately alerted to the environmental agency or other appropriate regulatory body. do not discharge into drains, water courses or onto the ground. spill clean up methods stop leak if possible without risk. absorb in vermiculite, dry sand or earth and place into containers. flush with plenty of water to clean spillage area. do not contaminate water sources or sewer. 7 handling and storage usage precautions avoid spilling, skin and eye contact. storage precautions store in tightly closed original container in a dry, cool and well-ventilated place. keep in original container. storage class chemical storage. 8 exposure controls/personal protection std stel - 15 min twa - 8 hrs name notes 200 ppm 600 mg/m3 wel 300 ppm 899 mg/m3 butanone sk 1000 ppm 1920 mg/m3 wel ethanol 50 ppm 154 mg/m3 wel 75 ppm 231 mg/m3 iso-butanol 50 ppm 191 mg/m3 wel 100 ppm 384 mg/m3 toluene sk 0.01 mg/m3 acgih zinc potassium chromate wel = workplace exposure limit. acgih = american conference of governmental industrial hygienists. sk = can be absorbed through skin. ingredient comments wel = workplace exposure limits protective equipment process conditions provide eyewash station. 6 2 / free datasheet http://
revision date 25/03/2011 TT-P-1757B type i class c yellow engineering measures provide adequate ventilation. observe occupational exposure limits and minimise the risk of inhalation of vapours. respiratory equipment no specific recommendation made, but respiratory protection may still be required under exceptional circumstances when excessive air contamination exists. hand protection use suitable protective gloves if risk of skin contact. eye protection if risk of splashing, wear safety goggles or face shield. other protection wear appropriate clothing to prevent any possibility of skin contact. hygiene measures do not smoke in work area! wash at the end of each work shift and before eating, smoking and using the toilet. promptly remove any clothing that becomes contaminated. use appropriate skin cream to prevent drying of skin. when using do not eat, drink or smoke. 9 physical and chemical properties appearance liquid odour mild characteristic of solvents boiling point (c) 76.7 - 157 relative density 1.218 evaporation rate <1 (etet=1) volatile by vol. (%) 60.13 flash point (c) -6.67 cc (closed cup). flammability limit - lower(%) 1.0 flammability limit - upper(%) 19 10 stability and reactivity stability stable under normal temperature conditions. conditions to avoid avoid excessive heat for prolonged periods of time. hazardous polymerisation will not polymerise. materials to avoid strong oxidising substances. strong alkalis. strong acids. hazardous decomposition products fire creates: carbon monoxide (co). carbon dioxide (co2). 11 toxicological information inhalation irritating to respiratory system. ingestion may cause stomach pain or vomiting. skin contact may cause sensitisation by skin contact. irritating to skin. eye contact irritating to eyes. 12 ecological information ecotoxicity toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 13 disposal considerations 6 3 / free datasheet http://
revision date 25/03/2011 TT-P-1757B type i class c yellow disposal methods dispose of waste and residues in accordance with local authority requirements. 14 transport information proper shipping name paint 1263 un no. road 3 adr class no. class 3: flammable liquids. adr class ii adr pack group (d/e) tunnel restriction code 33 hazard no. (adr) 3 adr label no. ?3ye hazchem code 1263 un no. sea 3 imdg class ii imdg pack gr. f-e, s-e ems 1263 un no. air 3 air class ii air pack gr. 15 regulatory information labelling toxic dangerous for the environment contains butanone ethanol iso-butanol mineral spirits stoddard solvent; low boiling point naphtha - unspecified talc toluene zinc potassium chromate risk phrases r22 harmful if swallowed. r36 irritating to eyes. r43 may cause sensitisation by skin contact. r45 may cause cancer. r50/53 very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. r65 harmful: may cause lung damage if swallowed. r67 vapours may cause drowsiness and dizziness. 6 4 / free datasheet http://
revision date 25/03/2011 TT-P-1757B type i class c yellow safety phrases s24/25 avoid contact with skin and eyes. s26 in case of contact with eyes, rinse immediately with plenty of water and seek medical advice. s37/39 wear suitable gloves and eye/face protection. s38 in case of insufficient ventilation, wear suitable respiratory equipment. s42 during fumigation/spraying wear suitable respiratory equipment. s45 in case of accident or if you feel unwell, seek medical advice immediately (show label where possible). s53 avoid exposure - obtain special instructions before use. s57 use appropriate containment to avoid environmental contamination. s60 this material and its container must be disposed of as hazardous waste. s61 avoid release to the environment. refer to special instructions/safety data sheets. p11 restricted to professional users. uk regulatory references fire precautions act 1971. health and safety at work act 1974. environmental listing control of pollution (special waste regulations) act 1980. eu directives dangerous preparations directive 1999/45/ec. regulation (ec) no 1907/2006 of the european parliament and of the council of 18 december 2006 concerning the registration, evaluation, authorisation and restriction of chemicals (reach), establishing a european chemicals agency, amending directive 1999/45/ec and repealing council regulation (eec) no 793/93 and commission regulation (ec) no 1488/94 as well as council directive 76/769/eec and commission directives 91/155/eec, 93/67/eec, 93/105/ec and 2000/21/ec, including amendments. statutory instruments the chemicals (hazard information and packaging for supply) regulations 2009 (s.i 2009 no. 716). approved code of practice safety data sheets for substances and preparations. classification and labelling of substances and preparations dangerous for supply. guidance notes workplace exposure limits eh40. chip for everyone hsg(108). national regulations health and safety at work act (as amended) 1974 the chemicals (hazard information and packaging for supply) regulations 2002. no. 1689. the carriage of dangerous goods and use of transportable pressure equipment regulations 2007 (cdg 2007) regulation (ec) no 1907/2006 of the european parliament and of the council of 18 december 2006 concerning the registration, evaluation, authorisation and restriction of chemicals (reach), establishing a european chemicals agency, amending directive 1999/45/ec and repealing council regulation (eec) no 793/93 and commission regulation (ec) no 1488/94 as well as council directive 76/769/eec and commission directives 91/155/eec, 93/67/eec, 93/105/ec and 2000/21/ec, including amendments. 16 other information issued by hs&e manager. revision date 25/03/2011 safety data sheet status approved. 6 5 / free datasheet http://
revision date 25/03/2011 TT-P-1757B type i class c yellow risk phrases in full flammable. r10 harmful by inhalation. r20 harmful if swallowed. r22 harmful: danger of serious damage to health by prolonged exposure through inhalation. r48/20 harmful: may cause lung damage if swallowed. r65 highly flammable. r11 irritating to eyes. r36 irritating to respiratory system and skin. r37/38 irritating to skin. r38 may cause cancer. r45 may cause sensitisation by skin contact. r43 possible risk of harm to the unborn child. r63 repeated exposure may cause skin dryness or cracking. r66 risk of serious damage to eyes. r41 vapours may cause drowsiness and dizziness. r67 very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. r50/53 disclaimer this information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. however, no warranty guarantee or representation is made to its accuracy, reliability or completeness. it is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use. 6 6 / free datasheet http://
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