safety data sheet loctite corporation 3951 environmental health & safety affairs 0158399a 5.00 ie ea 16.03.1999 msds_ie health & regulatory affairs - europe msds_ie page 1 of 4 this safety data sheet has been prepared in accordance with the requirements of ec directive 88/379/eec and 91/155/eec (and other related directives) and provides information relating to the safe handling and use of the product. 1. product and company information product code 0158399a trade name 3951 manufacturer/supplier loctite uk address watchmead, welwyn garden city, herts., al7ijb. phone number 01 707 358800 fax number 01 707 358900 emergency phone number +353-1-4599301/+353-1-87-2629625/+353-1-4046444 2. composition / information on ingredients nature polyurethane sealant. hazardous components in product for ec component name concentration r phrases classification ethylbenzene 1.00 - 5.00 r11, r20 f, xn diphenylmethane diisocyanate 1.00 - 5.00 r20, r36/37/38, r42 xn 2,2-dimorpholinodiethylether 0.10 - 0.50 r36/38 3. hazard identification irritating to eyes, respiratory system and skin. may cause sensitisation by inhalation. solvent will have a defatting action on the skin making it more susceptible to dermatitis and sensitisation. inhalation of vapours may cause headaches or dizziness. small quantities of isocyanate are produced when polyurethanes are heated above 150c or when they are involved in fire. tlv for isocyanate is .005ppm. inhalation of such vapour could provide an allergic reaction in sensitive individuals. 4. first aid measures first aid - inhalation remove affected person to fresh air, and if still feeling unwell seek medical attention. first aid - skin wash skin with plenty of soap and water. first aid - eyes flush eyes immediately with plenty of water for at least 15 minutes. volatile by-product released during polymerisation may cause irritation to eyes. first aid - ingestion rinse mouth with water then give plenty of water to drink. do not induce vomiting. seek medical advice.
safety data sheet loctite corporation 3951 environmental health & safety affairs 0158399a 5.00 ie ea 16.03.1999 msds_ie health & regulatory affairs - europe msds_ie page 2 of 4 5. fire fighting measures non flammable product (flash point is greater than 60c (cc)). if product is involved in fire extinguish with dry powder, foam or carbon dioxide. trace amounts of toxic fumes may be released on incineration and the use of breathing apparatus is recommended. self contained breathing apparatus should be worn when dealing with fire. 6. accidental release measures ventilate area. for small spills wipe up with paper towel and place in container for disposal. absorb spillage onto inert absorbent material such as sand or vermiculite and place in container for disposal. wash spillage site thoroughly with soap and water or detergent solution. 7. handling and storage handling use in a well ventilated area. vapours should be extracted to avoid inhalation. storage keep in a cool, well-ventilated area. storage temperature range 1c to 25c. 8. exposure controls / personal protection good industrial hygiene practices should be observed. wear suitable protective clothing. 9. physical and chemical properties physical state paste. colour black. odour mild. characteristic. ph - boiling range/point (c) - flash point (cc) (c) >60 specific gravity 1.12. solubility in water (kg/m3) insoluble. solubility in acetone partially soluble vapour pressure (mmhg @25c) less than 1 at 25 c. explosion limits (%) -
safety data sheet loctite corporation 3951 environmental health & safety affairs 0158399a 5.00 ie ea 16.03.1999 msds_ie health & regulatory affairs - europe msds_ie page 3 of 4 10. stability and reactivity the product is relatively stable under normal conditions of use. polymerisation will occur in the presence of moisture. 11. toxicological information inhalation this product may cause sensitisation by inhalation. prolonged exposure to high concentrations of vapours may lead to chronic effects in sensitive individuals. skin this product is classified as a skin irritant. eyes this product is an irritant to the eyes. ingestion this product is considered to be of low toxicity having an acute oral ld50 (rat) >2000mg/kg by analogy to other similar products. 12. ecological information keep away from drains and open waters. biological and chemical oxygen demands (bod and cod) of cured loctite products are insignificant. does not contain substances listed on the montreal protocol. in the cured state contribution of this product to environmental hazards is insignificant in comparison to articles in which it is used. precautions required with respect to environmental hazards of articles in which this product is used should be considered. 13. disposal considerations after use, tubes, cartons and bottles containing residual product should be disposed of as "chemically contaminated waste" in an authorised legal land fill site or incinerated. dispose of in accordance with local and national regulations. contribution of this product to waste is very insignificant in comparison to article in which it is used. regulations governing disposal of individual articles apply. 14. transport information un number none air (iata) not classified. sea (imo) not classified. road (adr)/rail (rid) not classified.
safety data sheet loctite corporation 3951 environmental health & safety affairs 0158399a 5.00 ie ea 16.03.1999 msds_ie health & regulatory affairs - europe msds_ie page 4 of 4 15. regulatory information contains contains isocyanates. see information supplied by the manufacturer. labelling information harmful none r phrases r36/37/38 irritating to eyes, respiratory system and skin. r42 may cause sensitisation by inhalation. s phrases s23 do not breathe vapour. s25 avoid contact with eyes. s26 in case of contact with eyes, rinse immediately with plenty of water and seek medical advice. s28 after contact with skin, wash immediately with plenty of soap and water. voluntary labelling n/a 16. other information msds first issued 14 november 1995 msds data revised 16 march 1999 prepared by: dr. prabhu kulkarni fici., miosh., mbira., senior chemist. health & regulatory affairs - europe further information may be obtained from:- loctite corporation, health and regulatory affairs - europe, tallaght business park, whitestown, dublin 24, ireland. tel: +353-1-4046444. fax: +353-1-4510806. supersedes safety data sheet no: 0158399a dated 14th october 1998 prepared by c.walsh the information in this safety data sheet was obtained from reputable sources and to the best of our knowledge is accurate and current at the mentioned date. neither loctite nor its subsidiary companies accept any liability arising out of the use of the information provided here or the use, application or processing of the product(s) described herein. attention of users is drawn to the possible hazards from improper use of the product(s).
|
